منابع مشابه
Preparation of 13C- and 3H-labeled cerulenin and biosynthesis with 13C-NMR.
Since the establishment of the mode of action of antifungal antibiotic cerulenin11 by BLOCH, O MURA, VAGELOS, and OTHERS,2 8) this antibiotic has become an important tool in the field of biochemistry as a specific inhibitor of lipid synthesis. In addition, cerulenin, [(2S)(3R)-2,3-epoxy-4-oxo-7,10-dodecadienoylamide],°' is one of the derivatives of dodecanoic acid and thus presents several feat...
متن کاملA 13C-NMR study of azacryptand complexes.
An azacryptand has been solubilised in aqueous media containing 50% (v/v) dimethyl sulphoxide. (13)C-NMR has been used to determine how the azacryptand is affected by zinc binding at pH 10. Using (13)C-NMR and (13)C-enriched bicarbonate we have been able to observe the formation of 4 different carbamate derivatives of the azacryptand at pH 10. The azacryptand was shown to solubilise zinc or cad...
متن کاملA 13C NMR study of methyl-branched hydrocarbon biosynthesis in the housefly.
Carbon 13 NMR, radiotracer and mass spectrometry studies were performed to confirm that propionate and methylmalonate are incorporated into long chain branched hydrocarbons as the methyl branch unit, to determine whether the branching methyl group was added initially or toward the end of the elongation process, to determine the precursor of methylmalonate, and to examine the metabolism of propi...
متن کاملSupramolecular interactions probed by 13C-13C solid-state NMR spectroscopy.
We present a robust solid-state NMR approach for the accurate determination of molecular interfaces in insoluble and noncrystalline protein-protein complexes. The method relies on the measurement of intermolecular (13)C-(13)C distances in mixtures of [1-(13)C]glucose- and [2-(13)C]glucose-labeled proteins. We have applied this method to Parkinson's disease-associated α-synuclein fibrils and fou...
متن کاملSYNTHESIS OF SOME SUBSTITUTED NAPHTHALENES VIA BENZYNE AND THEIR 13C-NMR AND 'H-NMR STUDIES
Aprotic diazotization of anthranilic acid with isoamylnitrite or amylnitrite gave benzenediazonium-2- carboxylate. Subsequent thermal decomposition of this diazonium salt (in situ) in 1,2-dichloroethane as a solvent at 85OC and in the presence of 2,5-diethyl-3,4-diphenylcyclopentadienonaes a trapping agent gave 1,4-diethyl-2, 3-diphenylnaphthalene in high yield, after loss of carbon monoxid...
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ژورنال
عنوان ژورنال: RADIOISOTOPES
سال: 1981
ISSN: 1884-4111,0033-8303
DOI: 10.3769/radioisotopes.30.special_61s